有机化学中的光谱方法-第6版 内容简介

本书是一本由英国剑桥大学d. h. williams和i. fleming合著的有机化学光谱方法经典教材。第1版出版于1966年，本书为第6版。书中讲述了近年来迅猛发展的二维核磁共振（如tocsy、远‘h-13c cosy）、maldi、ft-icr、tof等新技术。与时俱进，本版较前版在内容上做了较大的改动，有关uv和ir光谱的部分讲述的更加准确；丰富了关于nmr的内容；介绍ms的部分更加讲求结合实际。全书共分为五章，第1章为紫外和可见光谱，论述了电子吸收光谱在测定有机基团中的应用；第2章红外光谱，阐述了傅里叶红外和喇曼光谱的样品制备、光谱选律以及各官能团的特征吸收频率；第3章核磁共振波谱，主要介绍了‘h和13c核磁共振的经验参数、各种二维nmr的具体应用；第4章质谱，介绍了各种粒子谱以及气相和液相色谱与质谱的联用；第5章实例和习题，为读者提供了一些选自研究课题、具有启发性的实例，也为读者巩固所学的知识提供了练习。本书理论和实践并举，因此也适合有机化学工作者做为手册使用。读者对象：高校化学系师生、有关研究人员。

有机化学中的光谱方法-第6版 本书特色

《有机化学中的光谱方法(第6版)》是由世界图书出版公司出版的。

有机化学中的光谱方法-第6版 目录

PrefaceChapter 1: Ultraviolet and visible spectra1.1 Introduction1.2 Chromophores1.3 The absorption laws1.4 Measurement of the spectrum1.5 Vibrational fine structure1.6 Choice of solvent1.7 Selection rules and intensity1.8 Solvent effects1.9 Searching for a chromophore1.10 Definitions1.11 Conjugated dienes1.12 Polyenes1.13 Polyeneynes and poly-ynes1.14 Ketones and aldehydes; π-π* transitions1.15Ketones and aldehydes; π-π* transitions1.16α,β-Unsaturated acids, esters, nitriles and amides1.17The benzene ring1.18Substituted benzene rings1.19Polycyclic aromatic hydrocarbons1.20Heteroaromatic compounds1.21Quinones1.22Corroles, chlorins and porphyrins1.23Non-conjugated interacting chromophores1.24The effect ofsteric hindrance to coplanarity1.25Internet1.26BibliographyChapter 2: Infrared spectra2.1Introduction2.2Preparation of samples and examination in an infrared spectrometer2.3Examination in a Raman spectrometer2.4Selection rules2.5The infrared spectrum2.6The use of the tables of characteristic group frequencies2.7Absorption frequencies of single bonds to hydrogen 3600-2000 cm-2.8 Absorption frequencies of triple and cumulated double bonds2300-1930 cm-2.9 Absorption frequencies of the double-bond region 1900-1500 em-12.10Groups absorbing in the fingerprint region 2.11 Internet2.12Bibliography2.13 Correlation charts2.14Tables of dataChapter 3: Nuclear magnetic resonance spectra3.1 Nuclear spin and resonance3.2 The measurement of spectra3.3 The chemical shift3.4 Factors affecting the chemical shift3.4.1 Intramolecular factors affecting the chemical shift3.4.2 Intermolecular factors affecting the chemical shift3.5 Spin-spin coupling to 13C3.5.1 13C-2H Coupling3.5.2 13C-1H Coupling3.5.3 13C-13C Coupling3.6 1H-1H Vieinal coupling (3JHH)3.7 1H-1H Geminal coupling (2JHH)3.8 1H-1H Long-range coupling (4JHH and 5JHH)3.9 Deviations from first-order coupling3.10The magnitude of 1H-1H coupling constants3.10.1Vicinal coupling 3JHH3.10.2Geminal coupling (2JHH)3.10.3Long-range coupling (4JHH and 5JHH)3.11 Line broadening and environmental exchange3.11.1Efficient relaxation3.11.2Environmental exchange3.12Improving the NMR spectrum3.12.1The effect of changing the magnetic field3.12.2Shift reagents3.12.3Solvent effects3.13Spin decoupling3.13.1Simple spin decoupling3.13.2Difference decoupling3.14The nuclear Overhanser effect3.14.1Origins3.14.2NOE Difference spectra3.15Assignment ofCH3, CH2, CH and quaternary carbons in 13C NMR3.16Identifying spin systems——1D-TOCSY3.17 The separation of chemical shift and coupling onto different axes3.18 Two-dimensional NMR3.19 COSY spectra3.20 NOESY spectra3.21 2D-TOCSY spectra3.22 1H-13C COSY spectra3.22.1Heteronuclear Multiple Quantum Coherence (HMQC) spectra3.22.2Heteronuclear Multiple Bond Connectivity (HMBC) spectra3.23 Measuring 13C-IH coupling constants (HSQC-HECADE spectra)3.24 Identifying 13C-13C connections (INADEQUATE spectra)3.25 Three- and four-dimensional NMR3.26 Hints for spectroscopic interpretation and structure determination3.26.1 Carbon spectra3.26.2 Proton spectra3.26.3 Hetero-correlations3.27 Internet3.28 Bibliography3.29 Tables of dataChapter4: Mass spectra4.1 Introduction4.2 Ion production from readily volatile molecules4.2.1 Electron impact (EI)4.2.2 Chemical Ionisation (CI)4.3 Ion production from poorly volatile molecules4.3.1 Fast ion bombardment (FIB or LSIMS)4.3.2 Laser desorption (LD) and matrix-assisted laser desorption (MALDI)4.3.3 Electrospray ionisation (ESI)4.4 Ion analysis4.4.1 Magnetic analysers4.4.2 Combined magnetic and electrostatic analysers——high-resolution mass spectra (HRMS)4.4.3 Ion cyclotron resonance (ICR) analysers4.4.4 Time-of-flight (TOF) analysers4.4.5 Quadrupole analysers4.4.6 Ion-trap analysers4.5 Structural information from mass spectra4.5.1 Isotopic abundances4.5.2 EI spectra4.5.3 CI spectra4.5.4 FIB (LSMIS) spectra4.5.5 MALDI spectra4.5.6 ESI spectra4.5.7 ESI-FT-ICR and ESI-FT-Orbitrap spectra4.6 Separation coupled to mass spectrometry4.6.1 GC/MS and LC/MS4.6.2 MS/MS4.7 MS data systems4.8 Specific ion monitoring and quantitative MS (SIM and MIM)4.9 Interprcting the spectrum of an unknown4.10 Internet4.11 Bibliography4.12 Tables of dataChapter 5: Practice in structure determination5.1 General approach5.2 Simple worked examples using 13C NMR alone5.3 Simple worked examples using 1H N-MR alone5.4 Simple worked examples using the combined application of all fourspectroscopic ethods5.5 Simple problems using 13C NMR or joint application of IR and 13C NMR5.6 Simple problems using 1H NMR5.7 Problems using a combination of spectroscopic methods5.8 Answers to problems 1-33Index

有机化学中的光谱方法-第6版 节选

《有机化学中的光谱方法(第6版)》是一本由英国剑桥大学D. H. Williams和I. Fleming合著的有机化学光谱方法经典教材。第1版出版于1966年，《有机化学中的光谱方法(第6版)》为第6版。书中讲述了近年来迅猛发展的二维核磁共振（如Tocsy、远‘H-13C COSY）、MALDI、FT-ICR、TOF等新技术。与时俱进，本版较前版在内容上做了较大的改动，有关UV和IR光谱的部分讲述的更加准确；丰富了关于NMR的内容；介绍MS的部分更加讲求结合实际。全书共分为五章，第1章为紫外和可见光谱，论述了电子吸收光谱在测定有机基团中的应用；第2章红外光谱，阐述了傅里叶红外和喇曼光谱的样品制备、光谱选律以及各官能团的特征吸收频率；第3章核磁共振波谱，主要介绍了‘H和13C核磁共振的经验参数、各种二维NMR的具体应用；第4章质谱，介绍了各种粒子谱以及气相和液相色谱与质谱的联用；第5章实例和习题，为读者提供了一些选自研究课题、具有启发性的实例，也为读者巩固所学的知识提供了练习。《有机化学中的光谱方法(第6版)》理论和实践并举，因此也适合有机化学工作者做为手册使用。读者对象：高校化学系师生、有关研究人员。